Aerobic Copper‐Catalyzed Acetoxysulfenylation and Hydrosulfenylation of Alkenes with Thiols,ChemistrySelect

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Aerobic Copper‐Catalyzed Acetoxysulfenylation and Hydrosulfenylation of Alkenes with Thiols
ChemistrySelect ( IF 1.9 ) Pub Date : 2018-06-13 , DOI: 10.1002/slct.201801472
Nobukazu Taniguchi ₁

Affiliation

Copper‐catalyzed acetoxysulfenylation and hydrosulfenylation of alkenes using thiols were achieved. When a reaction was performed in acetic acid using CuI‐Phen⋅H₂O catalyst, the corresponding acetoxysulfides were obtained in excellent yields. This procedure could suppress the progress of hydroxysulfenylation or hydrosulfenylation. On the other hand, a reaction employing CuI‐TMEDA catalyst could undergo hydrosulfenylation through a radical process.

中文翻译：

铜与硫醇的需氧铜催化的乙酰氧基亚磺酰基化和氢磺基化

使用硫醇实现了铜催化的烯烃的乙酰氧基亚磺化和氢磺基化。当使用CuI-Phen·H ₂ O催化剂在乙酸中进行反应时，可以优良的产率获得相应的乙酰氧基硫化物。该程序可以抑制羟基亚磺酰化或氢磺酰化的进行。另一方面，使用CuI-TMEDA催化剂的反应可能会通过自由基过程进行氢磺酰化。

更新日期：2018-06-13

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