Atom‐Economical Applications of Diaryliodonium Salts,Chemistry - An Asian Journal

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Atom‐Economical Applications of Diaryliodonium Salts
Chemistry - An Asian Journal ( IF 3.5 ) Pub Date : 2018-08-01 , DOI: 10.1002/asia.201800609
Ming Wang ₁ , Shihao Chen ₁ , Xuefeng Jiang _{1,

2}

Affiliation

Diaryliodonium salt, as a stable and easily prepared reagent, has become one of the most efficient arylation reagents in organic synthesis. In traditional methods, this reagent is generally applied as a single arylation source and the regenerated aryl iodide is a waste of resources. In the past five years, transition‐metal‐catalyzed utilization of both aryl groups in diaryliodonium salts has been well demonstrated. The purpose of the present review is to focus on various atom‐economical applications of diaryliodonium salt methodologies that have been reported recently for the synthesis of functionalized molecules. The presentation is organized according to the structures of the diaryliodonium salts and the reaction components.

中文翻译：

Diaryliodonium盐的原子经济应用

二芳基碘鎓盐作为一种稳定且易于制备的试剂，已成为有机合成中最有效的芳基化试剂之一。在传统方法中，该试剂通常用作单一芳基化来源，而再生的芳基碘化物浪费资源。在过去的五年中，已经充分证明了过渡金属催化的对二芳基碘鎓盐中两个芳基的利用。本综述的目的是集中于最近报道的用于合成功能化分子的二芳基碘鎓盐方法的各种原子经济应用。该展示根据二芳基碘鎓盐的结构和反应组分进行组织。

更新日期：2018-08-01

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