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Ketone C–C Bond Activation Meets the Suzuki-Miyaura Cross-coupling
Chem ( IF 19.1 ) Pub Date : 2018-06-14 , DOI: 10.1016/j.chempr.2018.05.012
Xavier Just-Baringo , Igor Larrosa

In a recent issue of the Journal of the American Chemical Society, Dong and coworkers report that ketones can participate as electrophiles in the Suzuki-Miyaura cross-coupling reaction under Rh(I) catalysis. They show that activation of C–C bonds of unstrained ketones is a versatile process that can engage in cross-coupling reaction with aryl boronates.



中文翻译:

酮C–C键激活遇到铃木-宫浦的交叉耦合

在最近一期的《美国化学学会杂志》上,Dong及其同事报告说,在Rh(I)催化下,酮可作为亲电子试剂参与Suzuki-Miyaura的交叉偶联反应。他们表明,未应变的酮的C–C键的活化是一个通用的过程,可以与芳基硼酸酯发生交叉偶联反应。

更新日期:2018-06-14
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