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Intermolecular Metal-Catalyzed Reductive Coupling of Dienes, Allenes, and Enynes with Carbonyl Compounds and Imines
Chemical Reviews ( IF 51.4 ) Pub Date : 2018-06-13 00:00:00 , DOI: 10.1021/acs.chemrev.8b00213
Michael Holmes 1 , Leyah A. Schwartz 1 , Michael J. Krische 1
Affiliation  

Metal-catalyzed reductive coupling has emerged as an alternative to the use of stoichiometric organometallic reagents in an increasingly diverse range of carbonyl and imine additions. In this review, the use of diene, allene, and enyne pronucleophiles in intermolecular carbonyl and imine reductive couplings are surveyed, along with related hydrogen autotransfer processes.

中文翻译:

分子间金属催化的二烯,丙二烯和烯炔与羰基化合物和亚胺的还原偶联

金属催化的还原偶联已经成为取代化学计量的有机金属试剂的替代方案,在羰基和亚胺的添加范围越来越广。在这篇综述中,调查了二烯,丙二烯和烯炔前亲核试剂在分子间羰基和亚胺还原偶联中的使用,以及相关的氢自动转移过程。
更新日期:2018-06-13
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