A new protocol for the anti-Markovnikov hydrofunctionalization of alkenyl alcohol O-Bn ethers was developed using xanthates as functionalizing agents in the presence of lauroyl peroxide as a radical initiator and a stoichiometric oxidant. The benzyl group serves as a traceless hydrogen donor in the remote radical hydrogen atom transfer event during the process.

中文翻译：

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苄基醚作为无痕量氢供​​体在黄原酸酯对烯烃的反马尔可夫尼夫加氢官能化中的应用†

在月桂酰过氧化物作为自由基引发剂和化学计量氧化剂的情况下，使用黄原酸酯作为官能化剂，开发了一种新的烯基醇O -Bn醚抗Markovnikov加氢官能化方法。在该过程中，苄基在远程自由基氢原子转移过程中充当了无痕的氢供体。