Solvent-induced structural transformation and magnetic modulation in 1D copper(ii) polymers based on a semi-rigid ligand containing 4-amino-1,2,4-triazole†,CrystEngComm

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Solvent-induced structural transformation and magnetic modulation in 1D copper(ii) polymers based on a semi-rigid ligand containing 4-amino-1,2,4-triazole†
CrystEngComm ( IF 2.6 ) Pub Date : 2018-06-13 00:00:00 , DOI: 10.1039/c8ce00820e
Xiang-Wen Wu _{1,

2,

3,

4,

5} , Feng Pan _{1,

2,

3,

4,

5} , Shi Yin _{1,

2,

3,

4,

5} , Jing-Yuan Ge _{6,

7,

8,

9} , Guo-Xia Jin _{1,

2,

3,

4,

5} , Peng Wang _{9,

10,

11,

12} , Jian-Ping Ma _{1,

2,

3,

4,

5}

Affiliation

A helical Cu(II) polymer 1 exhibits reversible SCSC transformation and magnetism switch by the chemisorption/desorption of MeCN molecules. Significant changes in its color, coordination environment, and magnetic behavior were found during the SCSC transformation. In addition, the effect of different coordinated solvents on the magnetic properties was further investigated.

中文翻译：

溶剂诱导的一维铜（ii）聚合物的结构转变和磁调制，该聚合物基于含4-氨基-1,2,4-三唑的半刚性配体†

螺旋形的Cu（II）聚合物1通过MeCN分子的化学吸附/解吸表现出可逆的SCSC转变和磁性转换。在SCSC转换过程中，发现其颜色，配位环境和磁行为发生了显着变化。此外，进一步研究了不同配位溶剂对磁性的影响。

更新日期：2018-06-13

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