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Structure‐Specific Catalytic Oxidation with O2 by Isomers in Au28(SR)20 Nanoclusters
ChemistrySelect ( IF 2.1 ) Pub Date : 2018-06-12 , DOI: 10.1002/slct.201800914
Liqun Wang 1 , Xiaoqi Chai 1 , Xinglian Cheng 1 , Yan Zhu 1
Affiliation  

Au28(SPh‐tBu)20 and Au28(S‐c‐C6H11)20, which have the same Au20 kernel but different surface atom packing structure, serve as mode catalysts to investigate the influence of isomerism in catalysts on catalytic properties. Au28(SPh‐tBu)20 exhibited more efficient activity for the oxidation of cyclohexane and benzyl alcohol than Au28(S‐c‐C6H11)20.

中文翻译:

Au28(SR)20纳米团簇中异构体对O2的结构特定催化氧化

28(SPh-丁基)20和Au 28(S- ç -C 6 ħ 1120,其具有相同的Au 20的内核,但不同的表面原子的包装结构中,作为模式的催化剂来调查异构的在催化剂的影响催化性能。金28(SPh-丁基)20表现出更有效的酶活性比金环己烷和苯甲醇的氧化28(S- ç -C 6 ħ 1120
更新日期:2018-06-12
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