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PVP-assisted transformation of a metal–organic framework into Co-embedded N-enriched meso/microporous carbon materials as bifunctional electrocatalysts†
Chemical Communications ( IF 4.9 ) Pub Date : 2018-06-12 00:00:00 , DOI: 10.1039/c8cc02646g
Zuozhong Liang 1, 2, 3, 4, 5 , Chaochao Zhang 1, 2, 3, 4, 5 , Haitao Yuan 1, 2, 3, 4, 5 , Wei Zhang 1, 2, 3, 4, 5 , Haoquan Zheng 1, 2, 3, 4, 5 , Rui Cao 1, 2, 3, 4, 5
Affiliation  

A PVP-assisted pyrolysis strategy that can simply but efficiently transform zeolitic imidazolate framework-67 (ZIF-67) into a Co-embedded N-enriched meso/microporous carbon material (Co-NC) is reported for the first time. Without further acid treatment, Co-NC can reach an excellent electroactivity and long-term durability toward the oxygen-reduction reaction (ORR) and the oxygen-evolution reaction (OER).

中文翻译:

PVP辅助将金属有机框架转变为共嵌入的富氮的中孔/微孔碳材料,作为双功能电催化剂

首次报道了一种PVP辅助的热解策略,该策略可以简单但有效地将沸石咪唑酸酯骨架67(ZIF-67)转化为共嵌入的N富集的介孔/微孔碳材料(Co-NC)。无需进一步的酸处理,Co-NC就可以实现出色的电活性和对氧还原反应(ORR)和氧释放反应(OER)的长期耐久性。
更新日期:2018-06-12
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