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Waste and Virgin high-density poly(ethylene) into Renewable Hydrocarbons Fuel by pyrolysis-catalytic cracking with a CoCO 3 Catalyst
Journal of Analytical and Applied Pyrolysis ( IF 5.8 ) Pub Date : 2018-09-01 , DOI: 10.1016/j.jaap.2018.06.003
Man Vir Singh

Abstract Conversion of waste and virgin high-density poly(ethylene) (HD-PE) into renewable fuel/petrochemicals were carried out using a basic cobalt carbonate (CoCO3) catalysts by a pyrolysis-catalytic cracking process. The pyrolysis-catalytic cracking process provides an alternative clean fuel and also minimizes to the environmental problems by waste plastics. Renewable hydrocarbons fuel were analyzed by 2D-GC × GC/TOFMS, FT-IR spectroscopy, 1H NMR spectroscopy, CHNS/O analyzer, inductively coupled plasma (ICP) and its results found absolutely good hydrocarbon compounds as (in fuel were petrochemicals obtained from virgin plastic and waste HD-PE). Catalytic conversion rates of four experiments as virgin HD-PE into renewable hydrocarbons fuel was found 80%, 84.40%, 88.22%, 92%, light gases 19.69%, 15.35%, 11.53%, 7.77%, residues 0.31%, 0.28%, 0.25%, 0.30 recovered from the overall production. Catalytic conversion rates of four experiments as waste HD-PE into renewable hydrocarbons fuel was found 79%, 82%, 84%, 91%, light gases 20.50%, 17.55%, 15.65%, 8.59%, residues 0.50%, 0.49%, 0.35%, 0.41. Renewable hydrocarbon fuel was analyzed using ICP for sulfur contents, it was found very low sulfur content than ordinary fuel. It was observed that it is the only degradation of virgin and waste HD-PE but not creating any other reactions.

中文翻译:

使用 CoCO 3 催化剂通过热解催化裂化将废物和原始高密度聚(乙烯)转化为可再生烃燃料

摘要 使用碱式碳酸钴 (CoCO3) 催化剂通过热解-催化裂化工艺将废物和原始高密度聚乙烯 (HD-PE) 转化为可再生燃料/石化产品。热解-催化裂化工艺提供了一种替代的清洁燃料,也最大限度地减少了废塑料带来的环境问题。通过 2D-GC × GC/TOFMS、FT-IR 光谱、1H NMR 光谱、CHNS/O 分析仪、电感耦合等离子体 (ICP) 分析可再生碳氢燃料,其结果发现绝对好的碳氢化合物,因为(燃料中的石化产品来自于原始塑料和废 HD-PE)。四个实验的原始 HD-PE 转化为可再生碳氢化合物燃料的催化转化率分别为 80%、84.40%、88.22%、92%,轻气体 19.69%、15.35%、11.53%、7.77%、残留物 0.31%、0.28% 0. 25%,从总产量中回收 0.30。四个实验结果表明,废 HD-PE 转化为可再生碳氢燃料的催化转化率分别为 79%、82%、84%、91%、轻质气体 20.50%、17.55%、15.65%、8.59%、残留物 0.50%、0.49%、 0.35%、0.41。使用 ICP 分析可再生碳氢燃料的硫含量,发现硫含量比普通燃料低。据观察,这是原始和废弃 HD-PE 的唯一降解,但不会产生任何其他反应。发现它的硫含量比普通燃料低。据观察,这是原始和废弃 HD-PE 的唯一降解,但不会产生任何其他反应。发现它的硫含量比普通燃料低。据观察,这是原始和废弃 HD-PE 的唯一降解,但不会产生任何其他反应。
更新日期:2018-09-01
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