Iodine‐Catalyzed One‐Pot Decarboxylative Sulfenylation of Electron‐Rich Arenes and Indoles,ChemistrySelect

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Iodine‐Catalyzed One‐Pot Decarboxylative Sulfenylation of Electron‐Rich Arenes and Indoles
ChemistrySelect ( IF 1.9 ) Pub Date : 2018-06-11 , DOI: 10.1002/slct.201801119
Chitrakar Ravi ₁ , Rashmi Semwal ₁ , Rahul Kumar ₁ , Narreddula N. K. Reddy ₁ , Subbarayappa Adimurthy ₁

Affiliation

Elemental iodine catalyzed decarboxylative sulfenylation (mono‐ or di) of electron‐rich alkoxybenzoic acids using benzenesulfonohydrazides as sulfenylating agent for the synthesis of diaryl sulfides under transition metal‐free conditions has been described. The method also works for the decarboxylative thioarylation (mono‐ or di) of indole carboxylic acids. Reactions showed very good functional group tolerance and excellent yields of sulfinylated products.

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