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Recent advances in resolving kinetic and dynamic processes at the air/water interface using specular neutron reflectometry
Current Opinion in Colloid & Interface Science ( IF 7.9 ) Pub Date : 2018-06-11 , DOI: 10.1016/j.cocis.2018.06.002
Richard A. Campbell

This review addresses significant recent advances in kinetic and dynamic studies at the air/water interface using specular neutron reflectometry. A step change in the capabilities to resolve these processes in systems related to soft matter, biophysics, environment and health has been delivered primarily by the FIGARO instrument at the Institut Laue-Langevin. It is now routinely carried out to resolve the surface excess of single-component, deuterated monolayers on the second time scale and the interfacial composition of binary mixtures where only one component is deuterated on the minute time scale. This resource has been exploited extensively in the last few years to provide new insight into the kinetics of oxidation of monolayers targeted from the gas phase and the adsorption of various types of molecules from solution as well as the dynamic molecular interactions of systems under continuous flow and during repeated compression/expansion cycles of a Langmuir trough. A perspective is given on current capabilities and future developments that will result from further developments in instrumentation and sample environment.



中文翻译:

使用镜面中子反射仪解决空气/水界面动力学和动力学过程的最新进展

这篇综述阐述了使用镜面中子反射计在空气/水界面动力学和动力学研究方面的重大最新进展。Laue-Langevin研究所的FIGARO仪器主要实现了解决与软物质,生物物理,环境和健康相关的系统中这些过程的能力的逐步变化。现在常规地进行以在第二时间尺度上解决单组分氘化单层的表面过量和在分钟时间尺度上仅氘化一种组分的二元混合物的界面组成。在过去的几年中,该资源得到了广泛的利用,以提供新的见解,以气相为目标的单分子层的氧化动力学以及从溶液中吸附各种类型的分子,以及在连续流动和流动下系统的动态分子相互作用。在朗格缪尔谷的反复压缩/扩张周期中。给出了仪器和样品环境的进一步发展所带来的当前能力和未来发展的观点。

更新日期:2018-07-12
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