Light induced polyethylene ligation†,Polymer Chemistry

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Light induced polyethylene ligation†
Polymer Chemistry ( IF 4.1 ) Pub Date : 2018-06-11 00:00:00 , DOI: 10.1039/c8py00717a
Janin T. Offenloch _{1,

2,

3,

4,

5} , Sébastien Norsic _{6,

7,

8,

9,

10} , Hatice Mutlu _{1,

2,

3,

4,

5} , Manel Taam _{6,

7,

8,

9,

10} , Olivier Boyron _{6,

7,

8,

9,

10} , Christophe Boisson _{6,

7,

8,

9,

10} , Franck D'Agosto _{6,

7,

8,

9,

10} , Christopher Barner-Kowollik _{1,

2,

3,

4,

5}

Affiliation

We introduce a photoreactive polyethylene (PE) derivative, which upon light irradiation (λ_max = 365 nm) can effectively react to form well-defined block copolymers with polystyrene and poly(methyl methacrylate). The herein introduced synthetic technology provides challenging-to-access polyethylene architectures based on a rapid and catalyst free photochemical ligation concept.

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