Empowering mechanochemistry with multi-mechanophore polymer architectures,Polymer Chemistry

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Empowering mechanochemistry with multi-mechanophore polymer architectures
Polymer Chemistry ( IF 4.1 ) Pub Date : 2018-06-11 00:00:00 , DOI: 10.1039/c8py00720a
Brandon H. Bowser _{1,

2,

3,

4} , Stephen L. Craig _{1,

2,

3,

4}

Affiliation

The development of multi-mechanophore polymers (MMPs) has empowered new methodologies for observing, quantifying, and exploiting mechanochemical transformations. For example, techniques such as single molecule force spectroscopy and pulsed ultrasound can be used to induce and observe up to hundreds of chemical reactions within a single polymer, enabling mechanistic insights into mechanochemical reactivity. At the same time, MMPs allow for the substantial mechanochemical remodeling of polymers and associated changes in material properties. This minireview presents synthetic approaches that have been used to make MMPs, methods that have been developed to probe and characterize their reactivity, and changes in properties that have been observed through their mechanochemical response.

中文翻译：

借助多机理聚合物结构增强机理化学

多元力学聚合物（MMP）的发展为观察，定量和利用力学化学转化提供了新的方法。例如，诸如单分子力谱和脉冲超声的技术可用于在单个聚合物内诱导和观察多达数百种化学反应，从而实现对机械化学反应性的机械洞察力。同时，MMP可以对聚合物进行实质性的机械化学重塑以及相关的材料性能变化。这份小型回顾介绍了已用于制造MMP的合成方法，已开发出可探测和表征其反应性的方法以及通过其机械化学反应观察到的性质变化。

更新日期：2018-06-11

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