Transition Metal‐Free CO2 Fixation into New Carbon–Carbon Bonds,ChemSusChem

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Transition Metal‐Free CO2 Fixation into New Carbon–Carbon Bonds
ChemSusChem ( IF 7.5 ) Pub Date : 2018-08-07 , DOI: 10.1002/cssc.201801063
Alessio Cherubini-Celli ₁ , Javier Mateos ₁ , Marcella Bonchio ₁ , Luca Dell'Amico ₁ , Xavier Companyó ₁

Affiliation

CO₂ is the ultimate renewable carbon source on Earth and the essential C₁ building block for carbohydrate biosynthesis in photosynthetic organisms. Modern synthetic chemistry is facing the key challenge of developing fundamental transformations, such as C−C bond formation, in a sustainable and efficient manner from renewable sources. In this Minireview, the most significant methods recently reported for CO₂ fixation under transition metal‐free conditions are summarized, organized into three different chapters according to the nature of the chemical transformation that forges the new C−C bond. The focus is on the mechanistic aspects of the different CO₂ activation modes, with specific attention to those systems that operate under catalytic conditions.

中文翻译：

将无金属的二氧化碳固定过渡为新的碳-碳键

CO ₂是地球上最终的可再生碳源，也是光合作用生物中碳水化合物生物合成的基本C ₁组成部分。现代合成化学正面临着以可持续和高效的方式利用可再生资源发展诸如CC键形成等基本转变的关键挑战。在此Minireview中，总结了最近报道的在无过渡金属条件下用于CO ₂固定的最重要方法，根据形成新C-C键的化学转化的性质分为三章。重点是不同CO ₂的机械方面活化模式，特别注意那些在催化条件下运行的系统。

更新日期：2018-08-07

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