Bis(methoxypropyl) ether-promoted oxidation of aromatic alcohols into aromatic carboxylic acids and aromatic ketones with O2 under metal- and base-free conditions,Green Chemistry

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Bis(methoxypropyl) ether-promoted oxidation of aromatic alcohols into aromatic carboxylic acids and aromatic ketones with O2 under metal- and base-free conditions
Green Chemistry ( IF 9.3 ) Pub Date : 2018-06-08 , DOI: 10.1039/c8gc00223a
Kai-Jian Liu _{1,

2,

3,

4} , Si Jiang _{1,

2,

3,

4} , Ling-Hui Lu _{4,

5,

6,

7} , Ling-Li Tang _{1,

2,

3,

4} , Shan-Shan Tang _{1,

2,

3,

4} , Hai-Shan Tang _{1,

2,

3,

4} , Zilong Tang _{4,

8,

9,

10} , Wei-Min He _{1,

2,

3,

4,

5} , Xinhua Xu _{4,

5,

6,

7}

Affiliation

We describe an eco-friendly, practical and operationally simple procedure for the bis(methoxypropyl) ether-promoted oxidation of aromatic alcohols into aromatic carboxylic acids and aromatic ketones with atmospheric dioxygen as the sole oxidant. This chemical process is clean with high conversion and good selectivity, and an external initiator, catalyst, additive and base are not required. The virtue of this reaction is highlighted by its easily available and economical raw materials and excellent functional group tolerance (acid-, base- and oxidant-labile groups).

中文翻译：

在无金属和无碱条件下，双（甲氧基丙基）醚促进了O ₂将芳族醇氧化为芳族羧酸和芳族酮

我们描述了一种环保型，实用且操作简单的程序，用于将双（甲氧基丙基）醚促进的芳香族醇氧化成芳香族羧酸和芳香族酮，并以大气中的双氧作为唯一氧化剂。该化学过程是清洁的，具有高转化率和良好的选择性，并且不需要外部引发剂，催化剂，添加剂和碱。该反应的优点在于其易于获得，经济的原料以及出色的官能团耐受性（对酸，碱和氧化剂不稳定的基团）。

更新日期：2018-07-02

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