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A Practical Access to Functionalized Alkyl Sulfinates
Synlett ( IF 1.7 ) Pub Date : 2018-06-07 , DOI: 10.1055/s-0036-1591588
M. Haddad 1 , P. Phansavath 1 , V. Ratovelomanana-Vidal 1 , C. Tran 1 , B. Flamme 1 , A. Chagnes 1, 2
Affiliation  

We describe herein a three-step synthesis of aliphatic sulfinates. This cost-effective method involves the use of 2-mercaptobenzothiazole under mild conditions and exhibits good yields (up to 78% over three steps). This approach provides an access to a wide range of functionalized sulfinates. A good tolerance with respect to diverse functional groups (alkene, alkyne, ether, acetal) was also noted.

中文翻译:

实用的功能化烷基亚磺酸盐

我们在此描述了脂肪族亚磺酸盐的三步合成。这种具有成本效益的方法涉及在温和条件下使用 2-巯基苯并噻唑,并表现出良好的产率(三个步骤高达 78%)。这种方法提供了获得各种功能化亚磺酸盐的途径。还注意到对不同官能团(烯烃、炔烃、醚、缩醛)的良好耐受性。
更新日期:2018-06-07
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