Mesoporous cobalt/manganese oxide: a highly selective bifunctional catalyst for amine–imine transformations,Green Chemistry

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Mesoporous cobalt/manganese oxide: a highly selective bifunctional catalyst for amine–imine transformations
Green Chemistry ( IF 9.3 ) Pub Date : 2018-06-07 , DOI: 10.1039/c8gc00862k
Biswanath Dutta _{1,

2,

3,

4} , Seth March _{1,

2,

3,

4} , Laura Achola _{1,

2,

3,

4} , Sanjubala Sahoo _{2,

3,

4,

5} , Junkai He _{2,

3,

4,

5} , Alireza Shirazi Amin _{1,

2,

3,

4} , Yang Wu _{2,

3,

4,

5} , Shannon Poges _{1,

2,

3,

4} , S. Pamir Alpay _{2,

3,

4,

5} , Steven L. Suib _{1,

2,

3,

4,

5}

Affiliation

Herein, we discuss a heterogeneous catalytic protocol using cobalt doped mesoporous manganese oxide for amine–alcohol cross-coupling to selectively produce symmetric or asymmetric imines. Thorough investigations on the surface chemistry and physical properties of the material revealed its outstanding oxidation–reduction properties and reaction mechanism which was supported by quantum mechanical calculations done by using density functional theory (DFT).

中文翻译：

介孔钴/锰氧化物：用于胺-亚胺转化的高选择性双功能催化剂

在本文中，我们讨论了使用钴掺杂的中孔氧化锰进行胺-醇交叉偶联以选择性产生对称或不对称亚胺的非均相催化方案。对该材料的表面化学和物理性质进行了深入研究，发现其出色的氧化还原性质和反应机理得到了密度密度理论（DFT）的量子力学计算的支持。

更新日期：2018-07-16

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