Abstract In situ X-ray photoelectron spectroscopy real-time measurements and angular-dependent high resolution core level analysis were used for the first time to investigate the Cr enrichment and oxide growth mechanisms on a model 304 austenitic stainless steel surface in the very initial stages of oxidation leading to pre-passivation. The oxidation kinetics was followed for increasing oxygen exposure and temperature, revealing an early nucleation regime (for exposure

中文翻译：

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从单晶 Fe-18Cr-13Ni 的原位 XPS 分析对奥氏体不锈钢早期氧化阶段的新见解

摘要 首次使用原位 X 射线光电子能谱实时测量和角度相关的高分辨率核心水平分析来研究 304 型奥氏体不锈钢表面在初始阶段的 Cr 富集和氧化物生长机制。氧化导致预钝化。氧化动力学随着氧暴露和温度的增加而变化，揭示了早期的成核机制（对于暴露