Hyperbranched Polymers by Light‐Induced Self‐Condensing Vinyl Polymerization,Macromolecular Rapid Communications

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Hyperbranched Polymers by Light‐Induced Self‐Condensing Vinyl Polymerization
Macromolecular Rapid Communications ( IF 4.2 ) Pub Date : 2018-06-05 , DOI: 10.1002/marc.201800276
Cansu Aydogan ₁ , Mustafa Ciftci _{1,

2} , Yusuf Yagci _{1,

3}

Affiliation

Hyperbranched polymers (HBPs), a unique class of dendritic macromolecules, have received continuous interest from macromolecular scientists due to their inherent properties such as high level of functional terminal units, high solubility, and low viscosity. Despite enormous efforts devoted to the synthesis of HBPs by traditional methods such as single and double monomer strategies involving step‐growth polymerization and self‐condensing vinyl polymerization (SCVP) processes, there have been limited attempts to employ light‐induced processes. Photochemical methods, however, exhibit distinct advantages not characteristically disclosed by traditional ones, such as spatial and temporal control, low energy, and site‐specific activation. This review, after a brief summary of the conventional methods, presents the unique features and the key functionalities of the inimers for photoinduced SCVP and strategies for preparing HBPs.

中文翻译：

光诱导自缩合乙烯基聚合的超支化聚合物

超支化聚合物（HBPs）是一类独特的树枝状大分子，由于其固有的特性（例如高水平的功能性末端单元，高溶解性和低粘度）而受到了大分子科学家的持续关注。尽管通过传统方法（例如涉及逐步生长聚合和自缩合乙烯基聚合（SCVP）工艺的单单体和双单体策略）致力于合成HBP，但采用光诱导工艺的尝试有限。然而，光化学方法展现出传统方法未特有的独特优势，例如空间和时间控制，低能耗和特定位置活化。在对常规方法进行简要总结之后，本次审查

更新日期：2018-06-05

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