Externally controlled atom transfer radical polymerization,Chemical Society Reviews

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Externally controlled atom transfer radical polymerization
Chemical Society Reviews ( IF 40.4 ) Pub Date : 2018-06-05 00:00:00 , DOI: 10.1039/c8cs00259b
Xiangcheng Pan _{1,

2,

3,

4,

5} , Marco Fantin _{6,

7,

8,

9} , Fang Yuan _{1,

2,

3,

4,

5} , Krzysztof Matyjaszewski _{6,

7,

8,

9}

Affiliation

Spatial and temporal regulations of ATRP by external stimuli are presented. Various ATRP techniques, eATRP, photoATRP, and mechanoATRP, are controlled by electrical current, light, and mechanical forces, respectively. Conversely, ARGET and SARA ATRP are controlled by chemical reducing agents. ICAR ATRP is a thermally regulated process through decomposition of a radical initiator. The aim of this review is to highlight the use of external regulations in ATRP and to summarize the state-of-the-art and future perspectives, focusing on mechanistic aspects, synthetic procedures, preparation of polymers with complex architectures and functional materials, and their applications.

中文翻译：

外控原子转移自由基聚合

提出了外部刺激对ATRP的时空调控。各种ATRP技术，例如ATRP，photoATRP和mechanoATRP，分别由电流，光和机械力控制。相反，ARGET和SARA ATRP受化学还原剂控制。ICAR ATRP是通过自由基引发剂分解而进行的热调节过程。这篇综述的目的是强调在ATRP中使用外部法规并总结最新技术和未来观点，重点是机械方面，合成程序，具有复杂结构和功能材料的聚合物的制备及其应用。应用程序。

更新日期：2018-06-05

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