One-pot synthesis of ordered nanoporous amorphous H-Zn-aluminosilicate for catalysis of bulky molecules†,Sustainable Energy & Fuels

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One-pot synthesis of ordered nanoporous amorphous H-Zn-aluminosilicate for catalysis of bulky molecules†
Sustainable Energy & Fuels ( IF 5.0 ) Pub Date : 2018-06-05 00:00:00 , DOI: 10.1039/c8se00150b
Jitendra Diwakar _{1,

2,

3,

4,

5} , Nagabhatla Viswanadham _{1,

2,

3,

4,

5} , Saurabh Kumar _{1,

2,

3,

4,

5} , Adarsh Kumar _{1,

2,

3,

5,

6} , Sandeep K. Saxena _{2,

3,

4,

5,

7}

Affiliation

We are reporting a simple one-pot synthesis method of nanoporous H-zinc-aluminosilicate (HZnAlSi) from a Na-free chemical mixture. The material exhibits strong acidity required to catalyse bulky molecular reactions generally restricted in micro-porous zeolites. The material also exhibits superior catalytic properties giving as high as 99% glycerol conversion in glycerol acetylation, with stability and reusability.

中文翻译：

一锅法合成有序纳米多孔无定形H-Zn-铝硅酸盐以催化大分子†

我们正在报告一种从无钠的化学混合物中轻松合成纳米多孔H-锌-铝硅酸盐（HZnAlSi）的简单方法。该材料显示出催化通常在微孔沸石中受限的庞大分子反应所需的强酸度。该材料还具有优异的催化性能，在甘油乙酰化中可提供高达99％的甘油转化率，并具有稳定性和可重复使用性。

更新日期：2018-06-05

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