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Synthesis of polyoxomolybdate-quinoline compounds beads for catalytic oxidative desulfurization
Molecular Catalysis ( IF 3.9 ) Pub Date : 2018-06-02 , DOI: 10.1016/j.mcat.2018.02.014
Shuang Yue , Qian Song , Shuliang Zang , Guichun Deng , Jun Li

The polyoxomolybdate-quinoline compounds, [Cnquin]4Mo8O26 (Cnquin = N-alkylquinolinium, n = 2,5,8), have been successfully synthesized and characterized by 1H NMR, IR spectrum, elemental analysis and TGA, etc. The compounds have relatively high stability with decomposing temperature up to about 300 °C. Here the polyoxomolybdate-quinoline compounds were applied in removal of sulfur-containing compounds (benzothiophene [BT], dibenzothiophene [DBT] and thiophene [T]) in a system composed of model oil, 30% H2O2 and 1-octyl-3-methylimidazolium tetrafluoroborate ([C8mim]BF4). The effects of the ratio of H2O2 to model oil, the amount of catalyst, the structure of catalyst, the nature of sulfur-containing compounds and reaction temperature were studied to estimate the optimal conditions. The most suitable conditions were suggested: n (H2O2): n (DBT) = 4:1 and n (DBT): n (catalyst) = 100: 1, under 60 °C in 90 min. With the catalysts of [C2quin]4Mo8O26 [C5quin]4Mo8O26 and [C8quin]4Mo8O26, the removal of DBT could reach 98.4%, 98.5% and 99.2% respectively. The [C8quin]4Mo8O26 could be recycled for 5-times with a slight decrease in activity.



中文翻译:

用于催化氧化脱硫的聚氧钼酸喹啉化合物珠的合成

所述polyoxomolybdate -喹啉化合物,[C Ñ五重峰] 48 ø 26(C Ñ五重峰=  Ñ -alkylquinolinium,Ñ  = 2,5,8),已经成功地合成和表征通过1 H NMR,IR光谱,元素分析该化合物在分解温度高达约300°C时具有相对较高的稳定性。在此,将聚氧钼酸酯-喹啉化合物应用于由模型油,30%H 2 O 2和1-辛基-油组成的系统中,以去除含硫化合物(苯并噻吩[BT],二苯并噻吩[DBT]和噻吩[T])。3-甲基咪唑四氟硼酸盐([C 8mim] BF 4)。研究了H 2 O 2与模型油的比例,催化剂用量,催化剂结构,含硫化合物的性质和反应温度的影响,从而确定了最佳条件。建议最合适的条件:n(H 2 O 2):n(DBT)= 4:1,n(DBT):n(催化剂)= 100:1,在60°C下90分钟。用[C 2 quin] 4 Mo 8 O 26和[C 5 quin] 4 Mo 8 O 26和[C 8 quin] 4 Mo 8 O的催化剂如图26所示,DBT的去除率可分别达到98.4%,98.5%和99.2%。[C 8 quin] 4 Mo 8 O 26可以循环使用5次,但活性略有下降。

更新日期:2018-06-02
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