Yet again, new compounds found in systems with known binary phase diagrams. Synthesis, crystal and electronic structure of Nd3Bi7 and Sm3Bi7†,Chemical Communications

当前位置： X-MOL 学术 › Chem. Commun. › 论文详情

Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)

Yet again, new compounds found in systems with known binary phase diagrams. Synthesis, crystal and electronic structure of Nd3Bi7 and Sm3Bi7†
Chemical Communications ( IF 4.3 ) Pub Date : 2018-06-04 00:00:00 , DOI: 10.1039/c8cc02563k
Alexander Ovchinnikov _{1,

2,

3,

4,

5} , Julien P. A. Makongo _{1,

2,

3,

4,

5} , Svilen Bobev _{1,

2,

3,

4,

5}

Affiliation

The binary bismuthides Nd₃Bi₇ and Sm₃Bi₇ were synthesized and structurally characterized for the first time. The results from the calorimetric analysis show that both compounds are stable only up to about 500 °C, which may explain why they were overlooked during the original assessment of the corresponding phase diagrams.

中文翻译：