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Crystalline Ammonium Complexes of Trimethyl‐ and Triethylbenzene‐Based Tripodal Compounds Bearing Pyrazole and Indazole Groups
European Journal of Organic Chemistry ( IF 2.5 ) Pub Date : 2018-08-09 , DOI: 10.1002/ejoc.201800480
Mathias M. Schulze 1 , Niklas Koch 1 , Wilhelm Seichter 1 , Monika Mazik 1
Affiliation  

Ammonium complexes of pyrazole‐ or indazole‐bearing benzene‐based tripodal hosts were prepared and analysed by X‐ray diffraction. The crystal packings of the complexes are characterized by the presence of N–H/C–H···F hydrogen bonds as well as C–Br···N/π halogen bonds. Information about the conformations which adopt the tripodal molecules in the crystalline state is also provided by the performed analyses.
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中文翻译:

带有吡唑和吲唑基团的基于三甲基和三乙苯的三脚架化合物的结晶铵络合物

制备了吡唑基或吲唑基苯三脚架主体的铵盐配合物,并通过X射线衍射进行了分析。配合物的晶体堆积的特征是存在N–H / C–H ·· F氢键以及C–Br ··· N /π卤素键。通过进行的分析还提供了关于采用处于晶体状态的三脚架分子的构象的信息。
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更新日期:2018-08-09
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