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Mechanisms study of silicotungstic acid modified CeO2 catalyst for selective catalytic reduction of NOx with NH3: Effect of pH values
Journal of the Taiwan Institute of Chemical Engineers ( IF 5.7 ) Pub Date : 2018-06-01 , DOI: 10.1016/j.jtice.2018.05.018
Zhongxian Song , Lanying Wang , Qiulin Zhang , Ping Ning , Jia Hu , Tong Tang , Xin Liu , Bin Li

A series of silicotungstic acid modified CeO2 (SC-x, x represents the pH value of solution that is used for the preparation of catalysts) were prepared for the selective catalytic reduction (SCR) of NOx with NH3. SC-9 showed the best catalytic activity among the samples. The monodentate nitrate, bidentate nitrate, bridging nitrate and NO2 were detected over SC-9 and SC-10. Monodentate nitrate and bridging nitrate disappeared over SC-8. Furthermore, the monodentate nitrate and bridging nitrate could react with NH4+ on Brønsted acid sites to generate NH4NO3, and then was reduced by NO to form NO2, accompanied with the fast reaction between NO2 and coordinated NH3 on Lewis acid sites in the presence of gaseous NO. Besides, the SCR reaction pathway of SC catalysts followed by the Langmuir–Hinshelwood mechanism and the Eley–Rideal mechanism.



中文翻译:

硅钨酸修饰的CeO 2催化剂用NH 3选择性催化还原NO x的机理研究:pH值的影响

改性的CeO一系列硅钨酸2(SC- X,X代表一个用于催化剂的制备溶液pH值)中用于选择性催化还原(SCR)中制备的NO X与NH 3。SC-9在样品中显示出最佳的催化活性。在SC-9和SC-10上检测到了单齿硝酸盐,双齿硝酸盐,桥连硝酸盐和NO 2。单齿硝酸盐和桥连硝酸盐在SC-8上消失了。此外,单齿硝酸盐和桥连硝酸盐可与布朗斯台德酸位上的NH 4 +反应生成NH 4 NO 3,然后被NO还原形成NO 2。,伴随着气态NO存在下NO 2与配位NH 3在路易斯酸位上的快速反应。此外,SC催化剂的SCR反应路径依次为Langmuir-Hinshelwood机理和Eley-Rideal机理。

更新日期:2018-06-01
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