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Eco‐Friendly C–I and C–O Bond Formation of Simple Alkenes: Direct Access to β‐Iodo Oxyamines
ChemistrySelect ( IF 2.1 ) Pub Date : 2018-06-01 , DOI: 10.1002/slct.201800878
Kai Sun 1 , Saifei Zhang 1 , Zhenhua Liu 2 , Yunhe Lv 1
Affiliation  

A protocol has been established for iodine‐mediated C–I and C–O bond formation of alkenes, including vinylarenes, allylbenzenes, and simple heteroatom‐bearing cyclo‐ and linear alkenes. The approach provides a simple route to a series of structurally diverse β‐iodo oxyamines in moderate to excellent yields. The broad substrate scope, ease of large‐scale preparation, and potential for derivatization make this reaction attractive.

中文翻译:

简单烯烃的生态友好的C–I和C–O键形成:直接获得β-碘代氧胺

已经建立了一个用于碘介导的烯烃(包括乙烯基芳烃,烯丙基苯以及简单的带有杂原子的环烯和直链烯)的烯烃形成C-1和C-O键的规程。该方法为中等至极好的收率提供了一系列结构多样的β-碘氧胺的简单方法。广泛的底物范围,易于大规模制备以及衍生化的潜力使该反应具有吸引力。
更新日期:2018-06-01
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