Reusable N-Heterocyclic Carbene Complex Catalysts and Beyond: A Perspective on Recycling Strategies,Chemical Reviews

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Reusable N-Heterocyclic Carbene Complex Catalysts and Beyond: A Perspective on Recycling Strategies
Chemical Reviews ( IF 51.4 ) Pub Date : 2018-05-31 00:00:00 , DOI: 10.1021/acs.chemrev.8b00057
Wenlong Wang ₁ , Lifeng Cui ₁ , Peng Sun ₂ , Lijun Shi ₂ , Chengtao Yue ₂ , Fuwei Li ₂

Affiliation

With the continuous development of N-heterocyclic carbene (NHC) chemistry during the past decade, NHC metal complexes have gained wide applications in the research field of organometallic catalysis. The recycling and reuse of NHC metal complexes, which have undergone continuous expansion and diversification, can enhance their catalytic performance, extend their range of application, and afford new routes to green chemistry. Taking NHC metal complex catalysts as the main topic, this review intends to present a comprehensive study of recycling strategies of organometallic catalysts. By an elaborative summarization and classification of recycling strategies, a clear picture of all available of recycling strategies for organometallic catalysts is presented and the advantages and disadvantages of various recycling strategies for specific reactions are discussed in detail. This review is written with the hope of serving as a modest spur to induce other scientists’ further contributions in the fields of catalyst recycling and sustainable catalysis.

中文翻译：

可重复使用的N-杂环碳络合物催化剂及其他：回收策略的观点

随着近十年来N-杂环卡宾（NHC）化学的不断发展，NHC金属配合物在有机金属催化研究领域中获得了广泛的应用。经过不断扩展和多样化的NHC金属络合物的回收和再利用可以增强其催化性能，扩展其应用范围，并为绿色化学提供新的途径。本文以NHC金属络合物催化剂为主要主题，旨在对有机金属催化剂的循环利用策略进行全面的研究。通过详尽的总结和分类回收策略，给出了有机金属催化剂回收策略所有可用策略的清晰图片，并详细讨论了针对特定反应的各种回收策略的优缺点。撰写此评论的目的是希望能适度地激发其他科学家在催化剂循环利用和可持续催化领域的进一步贡献。

更新日期：2018-05-31

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