Visible light mediated desilylative C(sp2)–C(sp2) cross-coupling reactions of arylsilanes with aryldiazonium salts under Au(i)/Au(iii) catalysis†,Chemical Communications

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Visible light mediated desilylative C(sp2)–C(sp2) cross-coupling reactions of arylsilanes with aryldiazonium salts under Au(i)/Au(iii) catalysis†
Chemical Communications ( IF 4.3 ) Pub Date : 2018-05-31 00:00:00 , DOI: 10.1039/c8cc03925a
Indradweep Chakrabarty _{1,

2,

3,

4,

5} , Manjur O. Akram _{1,

2,

3,

4,

5} , Suprakash Biswas _{5,

6,

7,

8,

9} , Nitin T. Patil _{5,

6,

7,

8,

9}

Affiliation

Desilylative C(sp²)–C(sp²) cross-coupling reactions of arylsilanes with aryldiazonium salts under Au(I)/photoredox catalysis have been reported. The addition of Cu-salts as catalysts was found to be crucial for the success of this transformation.

中文翻译：

在Au（i）/ Au（iii）催化下，芳基硅烷与芳基重氮盐的可见光介导的脱甲硅烷基化C（sp ²）–C（sp ²）交叉偶联反应†

已经报道了在Au（I）/光氧化还原催化下，芳基硅烷与芳基重氮盐的脱甲硅基C（sp ²）-C（sp ²）交叉偶联反应。发现添加铜盐作为催化剂对于该转化的成功至关重要。

更新日期：2018-05-31

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