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Metal-organic framework (MOF)-based advanced sensing platforms for the detection of hydrogen sulfide
Trends in Analytical Chemistry ( IF 11.8 ) Pub Date : 2018-05-30 , DOI: 10.1016/j.trac.2018.05.013
Kumar Vikrant , Vanish Kumar , Yong Sik Ok , Ki-Hyun Kim , Akash Deep

Hydrogen sulfide (H2S) is and a colorless, corrosive, flammable, and toxic gas with a characteristic rotten egg smell. Although its detection can be conducted by conventional methods (like gas chromatography), highly effective and sensitive detection of H2S has been realized with the usage of various nanomaterials (e.g., carbon nanostructures, metal nanoparticles, metal oxide nanoparticles, and quantum dots). Metal-organic frameworks (MOFs), as employed for such applications either in their pristine or modified forms, have been recognized as the effective media for sensing of H2S due to synergistic effects in addition to their well-known merits (e.g., the large specific surface). This review has been organized to describe the potential applicability of MOF-based sensing against H2S through comparative evaluation of their capability against other materials or tools. We also discuss the present obstacles and outline the future scope of research on MOF-based sensing tools.



中文翻译:

基于金属有机框架(MOF)的先进传感平台,用于检测硫化氢

硫化氢(H 2 S)是一种无色,腐蚀性,易燃和有毒的气体,具有典型的鸡蛋臭味。尽管可以通过常规方法(例如气相色谱法)进行检测,但是通过使用各种纳米材料(例如碳纳米结构,金属纳米颗粒,金属氧化物纳米颗粒和量子点),已经实现了H 2 S的高效灵敏检测。金属有机框架(MOF),无论是原始形式还是改性形式,都已被认为是检测H 2的有效介质。由于其众所周知的优点(例如,大的比表面积),还具有协同效应。此次审查的目的是通过比较其与其他材料或工具的能力,来描述基于MOF的H 2 S传感技术的潜在适用性。我们还将讨论当前的障碍,并概述基于MOF的传感工具的未来研究范围。

更新日期:2018-07-12
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