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Ruthenium nanoparticles ligated by cholesterol-derived NHCs and their application in the hydrogenation of arenes†
Chemical Communications ( IF 4.3 ) Pub Date : 2018-05-29 00:00:00 , DOI: 10.1039/c8cc02833h
Lena Rakers 1, 2, 3, 4 , Luis M. Martínez-Prieto 5, 6, 7, 8, 9 , Angela M. López-Vinasco 5, 6, 7, 8, 9 , Karine Philippot 9, 10, 11, 12, 13 , Piet W. N. M. van Leeuwen 5, 6, 7, 8, 9 , Bruno Chaudret 5, 6, 7, 8, 9 , Frank Glorius 1, 2, 3, 4
Affiliation  

Herein we present ruthenium nanoparticles (Ru-NPs) stabilized with two rigid NHC ligands derived from cholesterol. The obtained nanoparticles were fully characterized and applied in the hydrogenation of various aromatic compounds under mild conditions. Interestingly, the more bulky ligand gives a slightly lower ligand coverage and a faster catalyst.

中文翻译:

胆固醇衍生的NHC连接的钌纳米颗粒及其在芳烃氢化中的应用

在这里,我们介绍了钌纳米颗粒(Ru-NPs),其由两个源自胆固醇的刚性NHC配体稳定。对获得的纳米颗粒进行了充分表征,并在温和条件下应用于各种芳族化合物的氢化。有趣的是,更大的配体会给出较低的配体覆盖率和更快的催化剂。
更新日期:2018-05-29
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