Journal of Nuclear Materials ( IF 2.8 ) Pub Date : 2018-05-29 , DOI: 10.1016/j.jnucmat.2018.05.060 Christian Chatillon , Ioana Nuta , Fatima-Zhara Roki , Evelyne Fischer
Thermodynamic data for the ruthenium oxide RuO2(s) are basic data for the calculation of gaseous release in the case of severe nuclear accident. The present study is a critical analysis of thermochemical data for RuO2(s) based on available published experimental data from calorimetry, vapor pressures in equilibrium with the diphasic RuRuO2 and Electromotive Force Measurements EMF. A full critical review and reinterpretation of data are presented in this work with a proposition of new and accurate data for RuO2(s): C°p (RuO2, s, 298.15 K) = 56.42 ± 0.08 J·K-1 ·mol-1, S°298.15 (RuO2,s) = 46.15 ± 0.05 J·K-1 ·mol-1, and Δ; fH298 (RuO2,s) = −312.3 ± 1.6 kJ.mol-1,
中文翻译:
RuO 2(s)的化学热力学
氧化钌RuO 2(s)的热力学数据是计算严重核事故时气体释放的基本数据。本研究是对RuO 2(s)的热化学数据的批判性分析,其依据是来自量热法,与两相Ru RuO 2平衡的蒸气压和电动势测量EMF的可用已公开实验数据。本文提出了对RuO 2(s)的新的准确数据的建议,对数据进行了全面的批判性审查和重新解释:C°p(RuO2,s,298.15 K)= 56.42±0.08 J·K-1·mol -1,S°298.15(RuO 2,s)= 46.15±0.05J·K-1·mol-1,Δ。fH298(RuO2,s)= −312.3±1.6 kJ.mol-1,