Increased rate of solvent diffusion in a prototypical supramolecular gel measured on the picosecond timescale†,Chemical Communications

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Increased rate of solvent diffusion in a prototypical supramolecular gel measured on the picosecond timescale†
Chemical Communications ( IF 4.3 ) Pub Date : 2018-05-29 00:00:00 , DOI: 10.1039/c8cc02962h
Tilo Seydel _{1,

2,

3} , Robert M. Edkins _{4,

5,

6,

7,

8} , Christopher D. Jones _{7,

9,

10} , Jonathan A. Foster _{7,

11,

12,

13} , Robert Bewley _{7,

14,

15,

16} , Juan A. Aguilar _{7,

17,

18,

19} , Katharina Edkins _{7,

9,

10}

Affiliation

Institut Laue-Langevin
Boulevard des Martyrs
France
Chemistry Research Laboratory
University of Oxford
Oxford
UK
Department of Pure and Applied Chemistry
School of Pharmacy
Queen's University Belfast
Department of Chemistry
Sheffield University
Sheffield
ISIS Neutron Facility
Rutherford Appleton Laboratory
Didcot
Chemistry Department
Durham University
Durham

Solvent diffusion in a prototypical supramolecular gel probed by quasi-elastic neutron scattering on the picosecond timescale is faster than that in the respective bulk solvent. This phenomenon is hypothesized to be due to disruption of the hydrogen bonding of the solvent by the large hydrophobic surface of the gel network.

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