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Increased rate of solvent diffusion in a prototypical supramolecular gel measured on the picosecond timescale†
Chemical Communications ( IF 4.3 ) Pub Date : 2018-05-29 00:00:00 , DOI: 10.1039/c8cc02962h
Tilo Seydel 1, 2, 3 , Robert M. Edkins 4, 5, 6, 7, 8 , Christopher D. Jones 7, 9, 10 , Jonathan A. Foster 7, 11, 12, 13 , Robert Bewley 7, 14, 15, 16 , Juan A. Aguilar 7, 17, 18, 19 , Katharina Edkins 7, 9, 10
Affiliation  

Solvent diffusion in a prototypical supramolecular gel probed by quasi-elastic neutron scattering on the picosecond timescale is faster than that in the respective bulk solvent. This phenomenon is hypothesized to be due to disruption of the hydrogen bonding of the solvent by the large hydrophobic surface of the gel network.

中文翻译:

在皮秒级的时间尺度上测得的原型超分子凝胶中溶剂扩散的速率增加

在皮秒级上通过准弹性中子散射探测的原型超分子凝胶中的溶剂扩散要快于各个本体溶剂中的扩散。推测该现象是由于凝胶网络的大疏水表面破坏了溶剂的氢键。
更新日期:2018-05-29
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