Autoinductive conversion of α,α-diiodonitroalkanes to amides and esters catalysed by iodine byproducts under O2†,Chemical Communications

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Autoinductive conversion of α,α-diiodonitroalkanes to amides and esters catalysed by iodine byproducts under O2†
Chemical Communications ( IF 4.3 ) Pub Date : 2018-05-25 00:00:00 , DOI: 10.1039/c8cc03191f
Jing Li _{1,

2,

3,

4,

5} , Martin J. Lear _{6,

7,

8,

9,

10} , Yujiro Hayashi _{1,

2,

3,

4,

5}

Affiliation

Studies to convert nitroalkanes into amides and esters using I₂ and O₂ revealed in situ-generated iodine species facilitate the homolytic C–I bond cleavage of α,α-diiodonitroalkanes, arguably in an autoinductive or autocatalytic manner. Consequently, we devised a rapid and economical I₂/O₂-based method to synthesise sterically hindered esters directly from primary nitroalkanes.

中文翻译：

在O ₂†下，碘副产物将α，α-二碘硝基烷烃自动感应转化为酰胺和酯。

使用I ₂和O ₂将硝基烷烃转化为酰胺和酯的研究表明，原位生成的碘可促进α，α-二碘硝基烷烃的均质C–I键裂解，可以说是自感应或自催化方式。因此，我们设计了一种快速且经济的基于I ₂ / O ₂的方法，直接从伯硝基烷烃中合成位阻酯。

更新日期：2018-05-25

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