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Hybrid Assembly of Different-Sized Supertetrahedral Clusters into a Unique Non-Interpenetrated Mn–In–S Open Framework with Large Cavity
Inorganic Chemistry ( IF 4.3 ) Pub Date : 2018-05-24 00:00:00 , DOI: 10.1021/acs.inorgchem.8b00907
Hongxiang Wang 1 , Wei Wang 1 , Dandan Hu 1 , Min Luo 1 , Chaozhuang Xue 1 , Dongsheng Li 2 , Tao Wu 1
Affiliation  

Reported here is a unique crystalline semiconductor open-framework material built from the large-sized supertetrahedral T4 and T5 clusters with the Mn–In–S compositions. The hybrid assembly between T4 and T5 clusters by sharing terminal μ2-S2– is for the first time observed among the cluster-based chalcogenide open frameworks. Such three-dimensional structure displays non-interpenetrated diamond-type topology with extra-large nonframework volume of 82%. Moreover, ion exchange, CO2 adsorption, as well as photoluminescence properties of the title compound are also investigated.

中文翻译:

将不同尺寸的超四面体簇混合组装成具有大空腔的独特的,非互穿的Mn-In-S开放框架

这里报道的是一种独特的晶体半导体开放框架材料,它由具有Mn-In-S成分的大型超四面体T4和T5团簇构建而成。通过共享终端μT4和T5簇之间装配的混合动力车2 -S 2-是用于基于群集的硫族化物的开放式架构中观察到的第一次。这种三维结构显示出非互穿的菱形拓扑,其中超大的非框架体积为82%。此外,还研究了标题化合物的离子交换,CO 2吸附以及光致发光性质。
更新日期:2018-05-24
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