Hybrid Assembly of Different-Sized Supertetrahedral Clusters into a Unique Non-Interpenetrated Mn–In–S Open Framework with Large Cavity,Inorganic Chemistry

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Hybrid Assembly of Different-Sized Supertetrahedral Clusters into a Unique Non-Interpenetrated Mn–In–S Open Framework with Large Cavity
Inorganic Chemistry ( IF 4.3 ) Pub Date : 2018-05-24 00:00:00 , DOI: 10.1021/acs.inorgchem.8b00907
Hongxiang Wang ₁ , Wei Wang ₁ , Dandan Hu ₁ , Min Luo ₁ , Chaozhuang Xue ₁ , Dongsheng Li ₂ , Tao Wu ₁

Affiliation

Reported here is a unique crystalline semiconductor open-framework material built from the large-sized supertetrahedral T4 and T5 clusters with the Mn–In–S compositions. The hybrid assembly between T4 and T5 clusters by sharing terminal μ₂-S^2– is for the first time observed among the cluster-based chalcogenide open frameworks. Such three-dimensional structure displays non-interpenetrated diamond-type topology with extra-large nonframework volume of 82%. Moreover, ion exchange, CO₂ adsorption, as well as photoluminescence properties of the title compound are also investigated.

中文翻译：

将不同尺寸的超四面体簇混合组装成具有大空腔的独特的，非互穿的Mn-In-S开放框架

这里报道的是一种独特的晶体半导体开放框架材料，它由具有Mn-In-S成分的大型超四面体T4和T5团簇构建而成。通过共享终端μT4和T5簇之间装配的混合动力车₂ -S ^2-是用于基于群集的硫族化物的开放式架构中观察到的第一次。这种三维结构显示出非互穿的菱形拓扑，其中超大的非框架体积为82％。此外，还研究了标题化合物的离子交换，CO ₂吸附以及光致发光性质。

更新日期：2018-05-24

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