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Mechanofluorochromic behavior of anthracene-based acylhydrazone derivatives
Tetrahedron ( IF 2.1 ) Pub Date : 2018-05-23 , DOI: 10.1016/j.tet.2018.05.058
Zhiming Li , Binglian Bai , Jue Wei , Haitao Wang , Qing Chai , Caijuan Sun , Min Li

Two anthracene-based derivatives, having one or two acylhydrazone branches attached on the anthracene, namely, asymmetrical AHP-1 and symmetrical AHBP-1 were designed. These compounds exhibited mechanofluorochromic behavior with the emission colors reversibly changing upon grinding and recrystallizing. The mechanofluorochromic mechanism was explored and ascribed to the crystalline-amorphous phase transformation. In addition, the red-shifted extent of fluorescent emission of the ground AHBP-1 samples was more than that of AHP-1.



中文翻译:

蒽基酰基hydr衍生物的机械荧光色行为

设计了两种蒽基衍生物,它们具有一个或两个连接在蒽上的酰基ac分支,即不对称的AHP-1和对称的AHBP-1。这些化合物表现出机械氟致变色行为,其发射颜色在研磨和重结晶时可逆地变化。探索了机械荧光致变色机理,并将其归因于结晶-非晶相变。此外,地面AHBP-1样品的荧光发射红移程度大于AHP-1。

更新日期:2018-05-23
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