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Single-crystalline thin-film growth via solution-mediated polymorphic transformation of octahexyl-substituted phthalocyanine and its optical anisotropy
Organic Electronics ( IF 2.7 ) Pub Date : 2018-05-22 , DOI: 10.1016/j.orgel.2018.05.029
Yusaku Anzai , Takuya Higashi , Hirotake Kajii , Akihiko Fujii , Masanori Ozaki

The fabrication of a single-crystalline thin film of non-peripheral octahexyl-phthalocyanine (C6PcH2) was realized by performing a tetrahydrofuran (THF) vapor treatment on a the spin-coated film. The solution-mediated polymorphic transformation of C6PcH2 was promoted in the THF vapor, and a single-crystalline thin film with α-phase crystal grew in the thin film when setting an appropriate temperature. The thin film exhibited optical anisotropy, such as a high dichroic ratio, and the color of the transmitted light varied from green to transparent depending on the polarization direction. The molecular packing structure on the substrate was determined by X-ray diffraction and polarized absorption measurements.



中文翻译:

通过溶液介导的八己基取代的酞菁多晶型转化及其光学各向异性的单晶薄膜生长

通过在旋涂膜上进行四氢呋喃(THF)蒸气处理,可以实现非周边八己基-酞菁(C6PcH 2)单晶薄膜的制造。在THF蒸气中促进了溶液介导的C6PcH 2的多晶型转变,并且当设定适当的温度时,具有α相晶体的单晶薄膜在薄膜中生长。薄膜表现出诸如高二向色比的光学各向异性,并且透射光的颜色根据偏振方向从绿色变为透明。通过X射线衍射和偏振吸收测量来确定在基板上的分子堆积结构。

更新日期:2018-05-22
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