当前位置: X-MOL 学术Polym. J. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Development of macromolecules and supramolecules based on silicon and arsenic chemistries
Polymer Journal ( IF 2.3 ) Pub Date : 2018-05-21 , DOI: 10.1038/s41428-018-0068-0
Hiroaki Imoto

AbstractOrganic–inorganic hybrids are one of the most important tools in materials science. Since the incorporation of abundant elements into single molecules realizes molecular-level hybridization, organic–inorganic hybrid molecules and polymers have attracted increasing attention. In this focus review, the author’s recent works on hybrid materials utilizing silicon and arsenic are overviewed. Among widely used silicon compounds, silsesquioxane ((RSiO1.5)n), adopting a cage structure, is a key structure. Polyhedral oligomeric silsesquioxane (POSS) has been employed for the reinforcement of organic materials, but the author has been working on “single-molecular POSS materials” and “main-chain-type POSS polymers.” In the last half of this review, organoarsenic polymers and supramolecules are introduced. Though experimental studies on organoarsenic compounds have been avoided due to the dangers of conventional synthetic procedures, the author’s practical methods have strongly contributed to the syntheses of functional organoarsenic compounds. The high functionality and usability of organoarsenic compounds are demonstrated.In this focus review, our recent progress on hybrid polymers and supramolecules utilizing silicon and arsenic is overviewed. Novel materials design based on polyhedral oligomeric silsesquioxane (POSS) has been realized by focusing on the symmetry. Practical synthetic methods have opened new avenue to experimental studies on organoarsenic compounds.

中文翻译:

基于硅和砷化学的大分子和超分子的开发

摘要有机-无机杂化物是材料科学中最重要的工具之一。由于将丰富的元素掺入单个分子中实现了分子水平的杂化,因此有机-无机杂化分子和聚合物越来越受到关注。在这篇焦点评论中,作者对利用硅和砷的混合材料最近的工作进行了概述。在广泛使用的硅化合物中,采用笼状结构的倍半硅氧烷((RSiO1.5)n)是关键结构。多面体低聚倍半硅氧烷 (POSS) 已被用于有机材料的增强,但作者一直致力于“单分子 POSS 材料”和“主链型 POSS 聚合物”。在本综述的后半部分,介绍了有机砷聚合物和超分子。尽管由于常规合成程序的危险性而避免了对有机砷化合物的实验研究,但作者的实用方法对功能性有机砷化合物的合成做出了重大贡献。展示了有机砷化合物的高功能性和可用性。在这篇重点综述中,我们概述了我们在利用硅和砷的杂化聚合物和超分子方面的最新进展。通过关注对称性,实现了基于多面体低聚倍半硅氧烷 (POSS) 的新型材料设计。实用的合成方法为有机砷化合物的实验研究开辟了新途径。作者的实用方法为功能性有机砷化合物的合成做出了重大贡献。展示了有机砷化合物的高功能性和可用性。在这篇重点综述中,我们概述了我们在利用硅和砷的杂化聚合物和超分子方面的最新进展。通过关注对称性,实现了基于多面体低聚倍半硅氧烷 (POSS) 的新型材料设计。实用的合成方法为有机砷化合物的实验研究开辟了新途径。作者的实用方法为功能性有机砷化合物的合成做出了重大贡献。展示了有机砷化合物的高功能性和可用性。在这篇重点综述中,我们概述了我们在利用硅和砷的杂化聚合物和超分子方面的最新进展。通过关注对称性,实现了基于多面体低聚倍半硅氧烷 (POSS) 的新型材料设计。实用的合成方法为有机砷化合物的实验研究开辟了新途径。通过关注对称性,实现了基于多面体低聚倍半硅氧烷 (POSS) 的新型材料设计。实用的合成方法为有机砷化合物的实验研究开辟了新途径。通过关注对称性,实现了基于多面体低聚倍半硅氧烷 (POSS) 的新型材料设计。实用的合成方法为有机砷化合物的实验研究开辟了新途径。
更新日期:2018-05-21
down
wechat
bug