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Anomalous thermally-activated NIR emission of ESIPT modulated Nd-complexes for optical fiber sensing devices†
Chemical Communications ( IF 4.9 ) Pub Date : 2018-05-21 00:00:00 , DOI: 10.1039/c8cc02345j
Si-Si Sun 1, 2, 3, 4, 5 , Jian-Hua Zhang 1, 2, 3, 4, 5 , Zheng Wang 1, 2, 3, 4, 5 , Yong-Qin Yu 6, 7, 8 , Cheng-Yi Zhu 1, 2, 3, 4, 5 , Mei Pan 1, 2, 3, 4, 5 , Cheng-Yong Su 1, 2, 3, 4, 5
Affiliation  

Highly sensitized NIR emission was modulated using an ESIPT ligand in a Nd-complex, to achieve a substantially elongated NIR lifetime in cyclohexane suspension with a value of 16.89 μs at RT, and anomalous themally-activated NIR emission with the temperature increasing from 77 to 300 K for the first time, which was further designed into a remote and in situ optical fiber sensing device.

中文翻译:

用于光纤传感设备的ESIPT调制Nd复合物的异常热激活NIR发射

使用ESIPT配体在Nd络合物中调节高度敏感的NIR发射,以在环己烷悬浮液中获得显着延长的NIR寿命,在RT下的值为16.89μs,并且随着温度从77升高至300,异常激活了NIR的发射K,这是第一次,它被进一步设计为远程和原位光纤传感设备。
更新日期:2018-05-21
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