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Bronsted Acid/Organic Photoredox Cooperative Catalysis: Easy Access to Tri- and Tetrasubstituted Alkenylphosphorus Compounds from Alcohols and P–H Species
Organic Letters ( IF 4.9 ) Pub Date : 2018-05-21 00:00:00 , DOI: 10.1021/acs.orglett.8b01173
Peizhong Xie 1 , Jing Fan 1 , Yanan Liu 1 , Xiangyang Wo 1 , Weishan Fu 1 , Teck-Peng Loh 1, 2, 3
Affiliation  

A Bronsted acid/organic photoredox cooperative catalytic system toward P–C bond formation from alcohols and P–H species is developed. With the assistance of visible light and TBHP, the reactions proceeded smoothly in an environmentally benign manner to give various alkenylphosphorus compounds in high efficiency.

中文翻译:

布朗斯台德酸/有机光氧化还原协同催化:从醇和PH物种容易获得三和四取代的烯基磷化合物

开发了一种布朗斯台德酸/有机光氧化还原协同催化系统,该催化系统可用于由醇和PH物质形成P-C键。在可见光和TBHP的辅助下,反应以对环境有益的方式顺利进行,从而高效地得到各种链烯基磷化合物。
更新日期:2018-05-21
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