meta‐ and para‐Selective C−H Functionalization using Transient Mediators and Noncovalent Templates,Asian Journal of Organic Chemistry

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meta‐ and para‐Selective C−H Functionalization using Transient Mediators and Noncovalent Templates
Asian Journal of Organic Chemistry ( IF 2.8 ) Pub Date : 2018-06-26 , DOI: 10.1002/ajoc.201800225
Munmun Ghosh ₁ , Suman De Sarkar ₁

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The efficient functionalization of nonactivated aromatic C−H bonds has emerged out as one of the most viable synthetic tools with respect to its versatile synthetic potential. The most successful approach for achieving positional selectivity has involved directing‐group manipulations. However, selective functionalization of distal C−H bonds, in particular those remote from the reactive functional group or the directing group, remains a daunting challenge in synthetic organic chemistry. However, several recent approaches have been developed to address this issue, including the use of transient mediators and noncovalent templates, which are discussed in this Focus Review.

中文翻译：

使用瞬时介体和非共价模板进行亚选择性和对选择性的CH功能化

就其通用的合成潜力而言，未活化的芳族CH键的有效功能化已成为最可行的合成工具之一。实现位置选择性的最成功方法是指挥组操纵。然而，远端CH键的选择性功能化，特别是那些远离反应性官能团或导向基团的CH键，在合成有机化学中仍然是一项艰巨的挑战。但是，已经开发出了几种解决此问题的新方法，包括使用瞬时介体和非共价模板，本“焦点回顾”中对此进行了讨论。

更新日期：2018-06-26

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