Metal-Free C(sp3)–H Allylation via Aryl Carboxyl Radicals Enabled by Donor–Acceptor Complex,Organic Letters

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Metal-Free C(sp3)–H Allylation via Aryl Carboxyl Radicals Enabled by Donor–Acceptor Complex
Organic Letters ( IF 4.9 ) Pub Date : 2018-05-16 00:00:00 , DOI: 10.1021/acs.orglett.8b01172
Yang Li ₁ , Jing Zhang ₁ , Defang Li _{1,

2} , Yiyun Chen _{1,

2}

Affiliation

The first aryl carboxyl radical generation by the donor–acceptor complex with N-acyloxyphthalimides and Hantzsch esters is reported. Regio- and chemoselective C(sp³)–H bond allylation is enabled by aryl carboxyl radicals with visible light irradiation under mild and metal-free conditions.

中文翻译：