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Metal-Free C(sp3)–H Allylation via Aryl Carboxyl Radicals Enabled by Donor–Acceptor Complex
Organic Letters ( IF 4.9 ) Pub Date : 2018-05-16 00:00:00 , DOI: 10.1021/acs.orglett.8b01172
Yang Li 1 , Jing Zhang 1 , Defang Li 1, 2 , Yiyun Chen 1, 2
Affiliation  

The first aryl carboxyl radical generation by the donor–acceptor complex with N-acyloxyphthalimides and Hantzsch esters is reported. Regio- and chemoselective C(sp3)–H bond allylation is enabled by aryl carboxyl radicals with visible light irradiation under mild and metal-free conditions.

中文翻译:

供体-受体配合物通过芳基羧基实现的无金属C(sp 3)-H烯丙基化

据报道,由供体-受体配合物与N-酰氧基邻苯二甲酰亚胺和Hantzsch酯产生的第一批芳基羧基自由基。区域和化学选择性的C(sp 3)–H键烯丙基化是由芳基羧基在可见光照射下在温和且无金属的条件下实现的。
更新日期:2018-05-16
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