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Synthesis of a superparamagnetic ultrathin FeCO3 nanorods–enzyme bionanohybrid as a novel heterogeneous catalyst†
Chemical Communications ( IF 4.9 ) Pub Date : 2018-05-16 00:00:00 , DOI: 10.1039/c8cc02851f
Rocio Benavente 1, 2, 3, 4 , David Lopez-Tejedor 1, 2, 3, 4 , Jose M. Palomo 1, 2, 3, 4
Affiliation  

Herein we report a straightforward synthesis of an ultrathin protein-iron(II) carbonate nanorods (FeCO3-NRs) heterogeneous bionanohybrid at room temperature and in aqueous media. The enzyme induced the in situ formation of well-dispersed FeCO3 NRs on a protein network. The addition of NaBH4 as a reducing agent allowed us to obtain nanorods (5 × 40 nm) with superparamagnetic properties. This bionanohybrid showed excellent catalytic results in reduction, oxidation and C–C bond reactions.

中文翻译:

超顺磁性超薄FeCO 3纳米棒-酶双离合杂化物的合成作为新型非均相催化剂

在这里,我们报告了一种在室温和水性介质中直接合成的超薄蛋白质-铁(II)碳纳米棒(FeCO 3 -NRs)异质双离合杂化物。该酶在蛋白质网络上诱导了分散良好的FeCO 3 NRs的原位形成。NaBH 4作为还原剂的加入使我们能够获得具有超顺磁性的纳米棒(5×40 nm)。该双离子杂化物在还原,氧化和CC键反应中显示出优异的催化效果。
更新日期:2018-05-16
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