Electron-poor arylenediimides,Organic Chemistry Frontiers

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Electron-poor arylenediimides
Organic Chemistry Frontiers ( IF 4.6 ) Pub Date : 2018-05-16 00:00:00 , DOI: 10.1039/c8qo00256h
Sharvan Kumar _{1,

2,

3,

4,

5} , Jyoti Shukla _{1,

2,

3,

4,

5} , Yogendra Kumar _{1,

2,

3,

4,

5} , Pritam Mukhopadhyay _{1,

2,

3,

4,

5}

Affiliation

Arylenediimides are inherently electron deficient and provide enormous opportunities to conjugate electron withdrawing substituents in different regions of the π-scaffold. This review article highlights the gradual emergence of diverse molecular design principles to realize exceptionally electron deficient arylenediimide molecules. Interestingly, non-conventional electron withdrawing substituents allow the realization of some of the strongest electron acceptors known from this class of molecules. Thus, an enthralling and exceptionally close race to garner the top position within the electron deficient molecules unfolds, which has immense implications with regard to stability and potential applications.

中文翻译：

贫电子亚芳基二酰亚胺

亚芳基二酰亚胺本质上是电子不足的，并提供了巨大的机会来共轭π支架不同区域中的吸电子取代基。这篇综述文章重点介绍了多种分子设计原理的逐步出现，以实现异常缺乏电子的亚芳基二酰亚胺分子。有趣的是，非常规的吸电子取代基允许实现从此类分子中已知的一些最强的电子受体。因此，为获得电子缺陷分子内的最高位置而进行的一场令人着迷的异常激烈的竞赛展开了，这对稳定性和潜在的应用具有巨大的影响。

更新日期：2018-05-16

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