Cobalt‐Catalyzed C(sp3)−H Functionalization Reactions,Asian Journal of Organic Chemistry

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Cobalt‐Catalyzed C(sp3)−H Functionalization Reactions
Asian Journal of Organic Chemistry ( IF 2.8 ) Pub Date : 2018-06-19 , DOI: 10.1002/ajoc.201800195
Tatsuhiko Yoshino ₁ , Shigeki Matsunaga ₁

Affiliation

C−H functionalization reactions hold great potential for the streamlined synthesis of complex molecules and are currently a “hot” topic in organic synthesis. Among the various transition metals that have been used, cobalt has recently attracted increased attention as a catalyst for C−H functionalization reactions, owing to its ready availability and high reactivity. Although a number of cobalt‐catalyzed C(sp²)−H functionalization reactions have been reported to date, C(sp³)−H functionalization reactions remain challenging. This Focus Review summarizes recent progress in cobalt‐catalyzed C(sp³)−H functionalization reactions that involve C−H activation to form organometallic intermediates.

中文翻译：

钴催化的C（sp3）-H官能化反应

CH官能化反应对于简化复杂分子的合成具有巨大潜力，目前是有机合成中的“热门”话题。在已使用的各种过渡金属中，钴由于其易于获得和高反应活性，最近已引起越来越多的关注，成为CH官能化反应的催化剂。尽管迄今为止已报道了许多钴催化的C（sp ²）-H功能化反应，但C（sp ³）-H功能化反应仍然具有挑战性。本焦点回顾总结了钴催化的C（sp ³）-H功能化反应的最新进展，该反应涉及CHH活化形成有机金属中间体。

更新日期：2018-06-19

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