Redox‐Responsive Polymer with Self‐Immolative Linkers for the Release of Payloads,Macromolecular Rapid Communications

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Redox‐Responsive Polymer with Self‐Immolative Linkers for the Release of Payloads
Macromolecular Rapid Communications ( IF 4.2 ) Pub Date : 2018-05-11 , DOI: 10.1002/marc.201800071
Supitchaya Iamsaard ₁ , Farzad Seidi ₁ , Naruphorn Dararatana ₁ , Daniel Crespy ₁

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Previous couplings of corrosion inhibitors to redox‐responsive polymers via covalent bonding suffer from several drawbacks. It is presented here novel redox‐responsive polymer‐corrosion inhibitor conjugates that contain self‐immolative linkers in their side chains. Very fast redox‐induced release of tryptamine, a drug and a corrosion inhibitor, is observed after applying a reductive trigger.

中文翻译：

带有自消灭性连接基的氧化还原反应性聚合物，可释放有效载荷

以前，腐蚀抑制剂通过共价键与氧化还原反应性聚合物的偶联存在多个缺点。本文介绍了新型的氧化还原反应性聚合物腐蚀抑制剂共轭物，其侧链中包含自消灭性连接基。施加还原性触发后，观察到氧化还原引起的色胺（一种药物和一种腐蚀抑制剂）的快速释放。

更新日期：2018-05-11

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