当前位置: X-MOL 学术Inorg. Chem. Front. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Facile synthesis of ultrathin and perpendicular NiMn2O4 nanosheets on reduced graphene oxide as advanced electrodes for supercapacitors†
Inorganic Chemistry Frontiers ( IF 7 ) Pub Date : 2018-05-11 00:00:00 , DOI: 10.1039/c8qi00121a
Long Li 1, 2, 3, 4, 5 , Hongli Hu 1, 2, 3, 4, 5 , Shujiang Ding 3, 6, 7, 8, 9
Affiliation  

Ultrathin nickel manganese oxide nanosheets grown vertically on reduced graphene oxide (NiMn2O4 NSs@rGO) were successfully fabricated through a facile co-precipitation and thermal treatment process. Such a unique nanostructure can not only facilitate electron transfer and electrolyte penetration but also withstand the structural damage of the active materials in electrochemical reactions. The resulting product NiMn2O4 NSs@rGO was characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS) and Brunauer–Emmett–Teller (BET) analysis. When evaluated for its potential as an electrode material in supercapacitors, the as-synthesized NiMn2O4 NSs@rGO nanocomposite exhibits enhanced energy storage performance with high specific capacitance (1243 F g−1 at 3 A g−1) and prominent cycle life (80.8% capacitance retention after 5000 cycles). These results indicate that the ultrathin and perpendicular NiMn2O4 nanosheets with rGO substrates obtained from this green and facile route hold great prospects in high performance supercapacitor applications.

中文翻译:

在还原的氧化石墨烯上作为超级电容器的先进电极,可 轻松合成超薄和垂直的NiMn 2 O 4纳米片

通过简便的共沉淀和热处理工艺成功制备了在氧化石墨烯(NiMn 2 O 4 NSs @ rGO)上垂直生长的超薄镍锰氧化物纳米片。这种独特的纳米结构不仅可以促进电子转移和电解质渗透,还可以承受电化学反应中活性物质的结构破坏。所得产物NiMn 2 O 4NSs @ rGO的特征在于X射线衍射(XRD),场发射扫描电子显微镜(FESEM),透射电子显微镜(TEM),X射线光电子能谱(XPS)和Brunauer–Emmett–Teller(BET)分析。当其作为超级电容器的电极材料评价的潜力,合成后原样的的NiMn 2 ö 4与高的比电容的NS @ RGO纳米复合材料表现出增强的能量储存性能(1243 F G -1在3 A G -1)和突出的循环寿命(5000次循环后的电容保持率为80.8%)。这些结果表明超薄和垂直的NiMn 2 O 4 通过这种绿色便捷的途径获得的带有rGO基底的纳米片在高性能超级电容器应用中具有广阔的前景。
更新日期:2018-05-11
down
wechat
bug