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Synergistic effect between Ag and Mn3O4 in the gas phase oxidation of alcohols
Catalysis Communications ( IF 3.4 ) Pub Date : 2018-05-09 , DOI: 10.1016/j.catcom.2018.05.002
Kun Liu , Tao Qin , Yongbin Sun , Chao Hou , Xiaoqun Cao , Shoujun Jiang

Ag2Mn5/SiC catalyst is simply obtained by in-situ reaction-induced of their corresponding nitrate compounds onto SiC support, which exhibits excellent catalytic activity and stability in the gas phase oxidation of alcohols (94% conversion of benzyl alcohol and 98% selectivity of benzaldehyde). The catalytic activity could maintain at least 300 h after four regenerations due to the formation of highly active Ag0-Mn3O4 species. XRD and XPS indicate that active Ag0-Mn3O4 species is formed from Ag2O and MnO2 in the reaction conditions. The synergistic effect between 34 nm Ag nanoparticles and 5.5 nm Mn3O4 nanoparticles in alcohol oxidation reaction is prominent, which is testified by HRTEM and three-step experiment.



中文翻译:

Ag和Mn 3 O 4在醇气相氧化中的协同作用

Ag 2 Mn 5 / SiC催化剂是通过将其相应的硝酸盐化合物原位反应诱导到SiC载体上而简单获得的,该化合物在醇的气相氧化中表现出出色的催化活性和稳定性(94%的苄醇转化率和98%的转化率)。苯甲醛的选择性)。由于形成了高活性的Ag 0 -Mn 3 O 4,四次再生后催化活性至少可以维持300 h 。XRD和XPS表明活性Ag 0 -Mn 3 O 4是由Ag 2 O和MnO 2形成的。在反应条件下。34nm Ag纳米颗粒和5.5nm Mn 3 O 4纳米颗粒在醇氧化反应中的协同作用很明显,这通过HRTEM和三步实验证明。

更新日期:2018-05-09
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