Recent progress in the stabilization of supramolecular assemblies with functional polydiacetylenes,Polymer Chemistry

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Recent progress in the stabilization of supramolecular assemblies with functional polydiacetylenes
Polymer Chemistry ( IF 4.1 ) Pub Date : 2018-05-07 00:00:00 , DOI: 10.1039/c8py00536b
M. Nazir Tahir _{1,

2,

3,

4} , Audithya Nyayachavadi _{1,

2,

3,

4} , Jean-François Morin _{4,

5,

6,

7} , Simon Rondeau-Gagné _{1,

2,

3,

4}

Affiliation

Supramolecular self-assembly is an increasingly popular approach to design and prepare functional materials, for various applications such as organic electronics and sensing. Despite allowing for a precise organization of photo- and electro-active building blocks, supramolecular assemblies often show poor kinetic stability, which limits their application. Among the recent strategies developed to circumvent this issue, the covalent stabilization of supramolecular self-assembly with polydiacetylene moieties is a particularly attractive approach to well-defined nanomaterials. In this review, we present the most recent examples of covalent rigidification of supramolecualr self-assemblies through the photopolymerization of diacetylene moieties. This approach has not only shown great promise for the stabilization of supramolecular assemblies through covalent bond formation, but also showed great promise for the rational design and preparation of well-defined carbon-rich materials.

中文翻译：

用功能性聚二乙炔稳定超分子组装的最新进展

超分子自组装是一种设计和制备功能材料的日益流行的方法，适用于各种应用，例如有机电子和传感。尽管允许精确地组织光敏和电活化的结构单元，但超分子组装体通常显示出较差的动力学稳定性，这限制了它们的应用。在为解决这个问题而开发的最新策略中，超分子自组装与聚二乙炔部分的共价稳定化是对定义明确的纳米材料特别有吸引力的方法。在这篇综述中，我们介绍了通过二乙炔部分的光聚合使超分子自组装体共价硬化的最新例子。

更新日期：2018-05-07

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