当前位置：
X-MOL 学术
›
Chem. Sci.
›
论文详情
Our official English website, www.x-mol.net, welcomes your
feedback! (Note: you will need to create a separate account there.)
Tropylium-promoted carbonyl–olefin metathesis reactions†
Chemical Science ( IF 7.6 ) Pub Date : 2018-05-04 00:00:00 , DOI: 10.1039/c8sc00907d Uyen P N Tran 1 , Giulia Oss 1 , Domenic P Pace 1 , Junming Ho 1 , Thanh V Nguyen 1
Chemical Science ( IF 7.6 ) Pub Date : 2018-05-04 00:00:00 , DOI: 10.1039/c8sc00907d Uyen P N Tran 1 , Giulia Oss 1 , Domenic P Pace 1 , Junming Ho 1 , Thanh V Nguyen 1
Affiliation
|
The carbonyl–olefin metathesis (COM) reaction is a highly valuable chemical transformation in a broad range of applications. However, its scope is much less explored compared to analogous olefin–olefin metathesis reactions. Herein we demonstrate the use of tropylium ion as a new effective organic Lewis acid catalyst for both intramolecular and intermolecular COM and new ring-opening metathesis reactions. This represents a significant improvement in substrate scope from recently reported developments in this field.
中文翻译：
Tropylium 促进的羰基-烯烃复分解反应†
羰基-烯烃复分解 (COM) 反应是一种在广泛应用中非常有价值的化学转化。然而，与类似的烯烃-烯烃复分解反应相比，其范围的探索要少得多。在此，我们展示了将鎓离子用作分子内和分子间 COM 和新的开环复分解反应的新型有效有机路易斯酸催化剂。与最近报道的该领域的发展相比，这代表了底物范围的显着改进。
更新日期：2018-05-04
中文翻译：
Tropylium 促进的羰基-烯烃复分解反应†
羰基-烯烃复分解 (COM) 反应是一种在广泛应用中非常有价值的化学转化。然而，与类似的烯烃-烯烃复分解反应相比，其范围的探索要少得多。在此，我们展示了将鎓离子用作分子内和分子间 COM 和新的开环复分解反应的新型有效有机路易斯酸催化剂。与最近报道的该领域的发展相比，这代表了底物范围的显着改进。
京公网安备 11010802027423号