当前位置: X-MOL 学术Chem. Phys. Lett. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Control of oleylamine to perovskite ratio in synthesis of MAPbBr3 nanoparticles
Chemical Physics Letters ( IF 2.8 ) Pub Date : 2018-05-01 , DOI: 10.1016/j.cplett.2018.04.057
Jing Huang , Yi-Hua Wu , Zhi-Gang Zhu , Wan Y. Shih , Wei-Heng Shih

Methylammonium lead bromide (CH3NH3PbBr3) nanocrystals have great potentials for lighting and display applications. Previously we synthesized CH3NH3PbBr3 nanocrystals using oleylamine as capping molecule and found that by increasing the oleylamine to CH3NH3PbBr3 perovskite ratio (OPR), the photoluminescence wavelengths and morphology of CH3NH3PbBr3 nanocrystals could be varied from 530 nm (green) platelets to 460 nm (blue) particles. Here we modified the synthesis to direct injection of precursors into toluene and found that increasing OPR not only changes the wavelength and morphology of nanocrystals but also the size of the unit cells.



中文翻译:

MAPbBr 3纳米粒子合成中油胺与钙钛矿比例的控制

甲基铵溴化铅(CH 3 NH 3 PbBr 3)纳米晶体在照明和显示应用中具有巨大潜力。以前,我们以油胺为封端分子合成了CH 3 NH 3 PbBr 3纳米晶体,发现通过提高油胺与CH 3 NH 3 PbBr 3钙钛矿的比例(OPR),可以得到CH 3 NH 3 PbBr 3的光致发光波长和形貌。纳米晶体可以从530 nm(绿色)血小板到460 nm(蓝色)颗粒变化。在这里,我们修改了合成方法,将前驱物直接注入甲苯中,发现增加的OPR不仅改变了纳米晶体的波长和形态,而且改变了晶胞的尺寸。

更新日期:2018-05-01
down
wechat
bug